Chemical weathering changes the composition of rocks, often transforming them when water interacts with minerals to create various chemical reactions. Chemical weathering is a gradual and ongoing process as the mineralogy of the rock adjusts to the near surface environment. New or secondary minerals develop from the original minerals of the rock. In this the processes of oxidation and hydrolysis are most important.
http://library.thinkquest.org/20035/chemical.htm
http://library.thinkquest.org/20035/chemical.htm